Polarony a jejich interakce se světlem

Školitel: Doc. Mgr. Martin Setvín, Ph.D.
Stav práce: volná

Anotace:
From a classical point of view, electrons and holes added to a semiconductor behave as delocalized plane waves. In ionic lattices, strong electrostatic interactions result in a spatial confinement of the charge carrier or its complete localization. The resulting quasiparticle is called a polaron [1] and it has wide impact on the materials properties and applications. The focus of this Thesis is the interaction of polarons with light, aiming either to probe the polarons’ properties, or to excite and manipulate these quasiparticles. While light is a powerful tool for studying and manipulating solid state, the spatial resolution of the associated techniques is fundamentally limited by the wavelength, providing area-averaged information. Recently, there has been a rapid progress in combining light with scanning probe techniques using plasmonic tips [2,3]. Amplification of the light intensity at the tip apex can reach a magnitude of 106, therefore allowing to achieve a sub-nanometer spatial resolution while maintaining the advantages of light. The aim of this Thesis is to use the combined STM/noncontact AFM [4] to study the behaviour of polarons in the real space with atomic precision and, combine the method with an optical setup that will allow additional employment of advanced methods based on light.

Literatura

[1] C. Franchini, M. Reticcioli, M. Setvin, U. Diebold, Polarons in Materials, Nature Reviews Materials 6, 560 (2021) [2] J. Lee et al., Visualizing vibrational normal modes of a single molecule with atomically confined light, Nature 568, 78 (2019) [3] F. Abajo et al., Roadmap for Photonics with 2D Materials, ACS photonics 12, 3961 (2025) [3] F. J. Giessibl, The qPlus sensor, a powerful core for the atomic force microscope, Rev. Sci. Instr. 90, 011101 (2019) [4] J. Redondo et al., Real-space investigation of polarons in hematite Fe2O3, Science Advances 10, eadp7833 (2024)